Isothiocyanate de méthyle (556-61-6)

General informations

Last verification the 03/02/2010

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Identification

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Numero CAS

556-61-6

Nom scientifique (FR)

Isothiocyanate de Méthyle

Nom scientifique (EN)

methylimino(sulfanylidene)methane

Autres dénominations scientifiques (Autre langues)

Isothiocyanatomethane ; Isothiocyanic acid, methyl ester ; Isotiocianato de metilo ; Isotiocianato di metile ; Methane, isothiocyanato- ; Methyl mustard ; Methyl mustard oil ; Methyl-isothiocyanat ; Methylisothiocyanaat (Netherlands) ; Methylisothiocyanat (Denmark) ; Methylisothiocyanate ; Methylisothiokyanat ; Methylsenfoel ; Metile isotiocianato

Code EC

209-132-5

Code SANDRE

2722

Number CIPAC

-

Formule chimique brute

\(\ce{ C2H3NS }\)

Code InChlKey

LGDSHSYDSCRFAB-UHFFFAOYSA-N

Code SMILES

N(=C=S)C

Families

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Usage families

Herbicide

CLP classification

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Type de classification

Harmonisée

ATP insertion

CLP00

Description de la classification

Classification harmonisée selon réglement 1272/2008 ou CLP

Hazard statements

H314

H301

H331

Toxique, irritant, sensibilisant, narcotique.

H317

Sensibilisant, cancérogène, mutagène, reprotoxique

H400

H410

Hazard statement - Code	H314
Hazard statement - Text	Provoque de graves brûlures de la peau et de graves lésions des yeux.
Hazard class(es)	Corrosion / Irritation cutanée
EU hazard label	-
Specific concentration limits	-
M factor	-
Acute toxicity estimate	-

ECHA sheet

Hazard statement - Code	H301
Hazard statement - Text	Toxique en cas d'ingestion
Hazard class(es)	Toxicité aiguë
EU hazard label	-

Hazard statement - Code	H331
Hazard statement - Text	Toxique par inhalation
Hazard class(es)	Toxicité aiguë
EU hazard label	-
Specific concentration limits	-
M factor	-
Acute toxicity estimate	-

ECHA sheet

Hazard statement - Code	H317
Hazard statement - Text	Peut provoquer une allergie cutanée
Hazard class(es)	Sensibilisation respiratoire/cutanée
EU hazard label	-
Specific concentration limits	-
M factor	-
Acute toxicity estimate	-

ECHA sheet

Hazard statement - Code	H400
Hazard statement - Text	Très toxique pour les organismes aquatiques
Hazard class(es)	Danger pour le milieu aquatique
EU hazard label	-

Hazard statement - Code	H410
Hazard statement - Text	Très toxique pour les organismes aquatiques, entraîne des effets à long terme
Hazard class(es)	Danger pour le milieu aquatique
EU hazard label	-
Specific concentration limits	-
M factor	-
Acute toxicity estimate	-

ECHA sheet

Regulations

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Règlement CLP - Annexe VI - Classification et étiquetage harmonisés pour certaines substances dangereuses

Physico Chemistry

Last verification the 03/02/2010

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Parameters table

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Parameters table
Value name	Value	Temperature	Pressure	Granulometry	Humidity	Guideline	ineris method	Commentary	Source
Coefficient de partage octanol/eau (Log Kow)	0.94 -						Expérimentation		Opasnet contributors

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Behavior

Last verification the 03/02/2010

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Matrixes

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Terrestrial environment

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Parameters table
Value name	Value	Temperature	Pressure	Granulometry	Humidity	Guideline	ineris method	Commentary	Source
Coefficient de partage carbone organique/Eau (Koc)	3 L.kg^-1						Expérimentation		Opasnet contributors

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Bioaccumulation

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Aquatic organisms

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Organismes aquatiques
ineris name	Specie	Value	Trofic level	Taxon	Matrix	Life stage	Effect	Detailed effect	Duration of exposure	ineris method	Guideline	Commentary	Source
Bioaccumulation BCF		3.162 -								Calcul			EPA

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Toxicology

Last verification the 03/02/2010

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Accidental values

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French acute toxicity threshold values

Expand/Collapse French acute toxicity threshold values

Le rapport de valeurs seuils de toxicité aiguë françaises est accessible dans la rubrique « Archives ». L’intégralité des rapports de valeurs seuils de toxicité aiguë françaises actuellement en vigueur est consultable dans le tableau des VSTAF.

French acute toxicity threshold values
ineris name	Unit	1 min	10 min	20 min	30 min	60 min	120 min	240 min	480 min	Status state	Commentary
SELS (SELS 5%)	ppm	870	404	321	280	222	176	140	70	Final
SELS (SELS 5%)	mg.m^-3	2601	1208	960	837	664	526	419	209	Final
SPEL (SEL 1%)	ppm	789	366	291	254	202	160	127	64	Final
SPEL (SEL 1%)	mg.m^-3	2359	1094	870	759	604	478	380	191	Final
SEI	ppm	88	41	32	28	22	18	14	7	Final
SEI	mg.m^-3	262	122	97	84	67	53	42	21	Final
SER	ppm	ND	0,63	0,63	0,27	0,27	0,27	0,27	ND	Final	Non Déterminé
SER	mg.m^-3	ND	1,89	1,89	0,81	0,81	0,81	0,81	ND	Final	Non Déterminé

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Other accidental thresholds

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Other accidental thresholds
ineris name	Duration	Value	Source	Status state	Commentary
AEGL-1	10 min	0,27 ppm	EPA	Final
AEGL-1	30 min	0,27 ppm	EPA	Final
AEGL-1	60 min	0,27 ppm	EPA	Final
AEGL-1	240 min	0,27 ppm	EPA	Final
AEGL-1	480 min	0,27 ppm	EPA	Final
AEGL-2	10 min	21 ppm	EPA	Final
AEGL-2	30 min	21 ppm	EPA	Final
AEGL-2	60 min	17 ppm	EPA	Final
AEGL-2	240 min	10 ppm	EPA	Final
AEGL-2	480 min	5,3 ppm	EPA	Final
AEGL-3	10 min	63 ppm	EPA	Final
AEGL-3	30 min	63 ppm	EPA	Final
AEGL-3	60 min	50 ppm	EPA	Final
AEGL-3	240 min	31 ppm	EPA	Final
AEGL-3	480 min	16 ppm	EPA	Final
PAC-1	60 min	0,27 ppm	EHSS (2018)	Final	AEGL-1, AEGL-2, AEGL-3
PAC-2	60 min	17 ppm	EHSS (2018)	Final	AEGL-1, AEGL-2, AEGL-3
PAC-3	60 min	50 ppm	EHSS (2018)	Final	AEGL-1, AEGL-2, AEGL-3

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