P-toluidine (106-49-0)

General informations

Last verification the 12/12/2005

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Identification

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Numero CAS

106-49-0

Nom scientifique (FR)

p-Toluidine

Nom scientifique (EN)

4-methylaniline

Autres dénominations scientifiques (Autre langues)

4-aminotoluene ; 4-methylaniline ; 4-aminotoluenas ; 4-aminotolueno ; 4-methylanilin ; p-toluidina

Code EC

203-403-1

Code SANDRE

3359

Number CIPAC

-

Formule chimique brute

\(\ce{ C7H9N }\)

Code InChlKey

RZXMPPFPUUCRFN-UHFFFAOYSA-N

Code SMILES

Nc(ccc(c1)C)c1

CLP classification

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Type de classification

Harmonisée

ATP insertion

CLP00

Description de la classification

Classification harmonisée selon réglement 1272/2008 ou CLP

Hazard statements

H301

H311

H331

Toxique, irritant, sensibilisant, narcotique.

H317

H319

Sensibilisant, cancérogène, mutagène, reprotoxique

H351

H400

Hazard statement - Code	H301
Hazard statement - Text	Toxique en cas d'ingestion
Hazard class(es)	Toxicité aiguë
EU hazard label	-

Hazard statement - Code	H311
Hazard statement - Text	Toxique par contact cutané
Hazard class(es)	Toxicité aiguë
EU hazard label	-

Hazard statement - Code	H331
Hazard statement - Text	Toxique par inhalation
Hazard class(es)	Toxicité aiguë
EU hazard label	-
Specific concentration limits	-
M factor	-
Acute toxicity estimate	-

ECHA sheet

Hazard statement - Code	H317
Hazard statement - Text	Peut provoquer une allergie cutanée
Hazard class(es)	Sensibilisation respiratoire/cutanée
EU hazard label	-

Hazard statement - Code	H319
Hazard statement - Text	Provoque une sévère irritation des yeux
Hazard class(es)	Lésions oculaires graves/irritation oculaire
EU hazard label	-
Specific concentration limits	-
M factor	-
Acute toxicity estimate	-

ECHA sheet

Hazard statement - Code	H351
Hazard statement - Text	Susceptible de provoquer le cancer (indiquer la voie d'exposition s'il est formellement prouvé qu'aucune autre voie d'exposition ne conduit au même danger)
Hazard class(es)	Cancerogénicité
EU hazard label	-
Specific concentration limits	-
M factor	-
Acute toxicity estimate	-

ECHA sheet

Hazard statement - Code	H400
Hazard statement - Text	Très toxique pour les organismes aquatiques
Hazard class(es)	Danger pour le milieu aquatique
EU hazard label	-
Specific concentration limits	-
M factor	-
Acute toxicity estimate	-

ECHA sheet

Regulations

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Règlement CLP - Annexe VI - Classification et étiquetage harmonisés pour certaines substances dangereuses

Physico Chemistry

Last verification the 12/12/2005

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Generalities

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Poids moléculaire

107.16 g/mol

Parameters table

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Parameters table
Value name	Value	ineris method	Commentary	Source
Hydrosolubilité	7400 mg.L^-1		à 25°C	UNEP (2007)
Densité	0.9619 -			UNEP (2007)
Pression de vapeur	38.1 Pa		à 25°C	UNEP (2007)
Point de fusion	44 °C			UNEP (2007)
Constante de Henry	0.2 Pa.m³.mol^-1		mesurée à 25°C	UNEP (2007)
Coefficient de partage octanol/eau (Log Kow)	1.39 -		mesuré	UNEP (2007)
Coefficient de partage octanol/eau (Log Kow)	1.39 -	Expérimentation		EPA

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Behavior

Last verification the 12/12/2005

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Matrixes

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Terrestrial environment

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Parameters table
Value name	Value	Temperature	Pressure	Granulometry	Humidity	Guideline	ineris method	Commentary	Source
Coefficient de partage carbone organique/Eau (Koc)	112.7 L.kg^-1						Calcul		EPA
Coefficient de partage carbone organique/Eau (Koc)	72.5 L.kg^-1							calculé	UNEP (2007)

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Persistence

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Biodegradability

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Parameters table
Value name	Value	Temperature	Pressure	Granulometry	Humidity	Guideline	ineris method	Commentary	Source
Biodégradabilité	intrinsèquement biodégradable -

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Abiotic degradability

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Parameters table
Value name	Value	Temperature	Pressure	Granulometry	Humidity	Guideline	ineris method	Commentary	Source
Photolyse	0.12 jour							calculée	UNEP (2007)

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Bioaccumulation

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Aquatic organisms

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Organismes aquatiques
ineris name	Specie	Value	Trofic level	Taxon	Matrix	Life stage	Effect	Detailed effect	Duration of exposure	ineris method	Guideline	Commentary	Source
Bioaccumulation BCF		1.3 -										poisson - valeur maximale mesurée pour une concentration de 0.1 mg/L	UNEP (2007)
Bioaccumulation BCF		13 -										poisson - valeur maximale mesurée pour une concentration de 0.01mg/L	UNEP (2007)

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Toxicology

Last verification the 12/12/2005

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Accidental values

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Other accidental thresholds

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Other accidental thresholds
ineris name	Duration	Value	Source	Status state	Commentary
PAC-1	60 min	6 ppm	EHSS (2018)	Final	TLV-TWA x 3, rat oral TDLo, rat oral LD50
PAC-2	60 min	8,2 ppm	EHSS (2018)	Final	TLV-TWA x 3, rat oral TDLo, rat oral LD50
PAC-3	60 min	30 ppm	EHSS (2018)	Final	TLV-TWA x 3, rat oral TDLo, rat oral LD50

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Ecotoxicology

Last verification the 12/12/2005

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Hazards

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Hazard values

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Environment

Valeurs de danger
ineris name	Value	Taxon	Source
CL/CE50	32.9 mg.L^-1	Algue	UNEP (2007)
CL/CE50	0.12 mg.L^-1	Invertebré	UNEP (2007)
CL/CE50	10.7 mg.L^-1	Poisson	UNEP (2007)

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Ecotoxicological values

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Guide values

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Environment

Valeurs guides
ineris name	Value	Matrix	Target	Critical effect retained	Duration of exposure	Factor	Commentary	Status state	Value retained by INERIS	Year	Source
PNEC chronique / AA-QSwater_eco	0.00012 mg.L^-1	Eau douce				1000	extrapolation		Yes		UNEP (2007)

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