Tétrahydrofuranne (109-99-9)

General informations

Last verification the 26/11/2020

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Identification

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Numero CAS

109-99-9

Nom scientifique (FR)

Tétrahydrofurane

Nom scientifique (EN)

oxolane

Autres dénominations scientifiques (Autre langues)

tetrahidrofuranas ; tetrahidrofurano ; Furan, tetrahydro- ; 1,4-Epoxybutane ; 1,4-Epoxybutane Oxacyclopentane or Oxolane ; 1-Oxacyclopentan ; 2-Butenedioic acid (2Z)-, cyclohexyl 2-methylpropyl ester ; Oxacyclepenthane ; THF ; oxolane ; Cyclotetramethylene oxide

Code EC

203-726-8

Code SANDRE

1582

Number CIPAC

-

Formule chimique brute

\(\ce{ C4H8O }\)

Code InChlKey

WYURNTSHIVDZCO-UHFFFAOYSA-N

Code SMILES

O(CCC1)C1

CLP classification

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Type de classification

Harmonisée

ATP insertion

CLP00/ATP03

Description de la classification

Classification harmonisée selon réglement 1272/2008 ou CLP

Hazard statements

H225

Toxique, irritant, sensibilisant, narcotique.

H319

H335

Sensibilisant, cancérogène, mutagène, reprotoxique

H351

Hazard statement - Code	H225
Hazard statement - Text	Liquide et vapeurs très inflammables
Hazard class(es)	Liquides inflammables
EU hazard label	-
Specific concentration limits	STOT SE 3;H335: C ≥ 25 % Eye Irrit.2;H319: C ≥ 25 %
M factor	-
Acute toxicity estimate	-

ECHA sheet

Hazard statement - Code	H319
Hazard statement - Text	Provoque une sévère irritation des yeux
Hazard class(es)	Lésions oculaires graves/irritation oculaire
EU hazard label	-

Hazard statement - Code	H335
Hazard statement - Text	Peut irriter les voies respiratoires
Hazard class(es)	Toxicité spécifique pour certains organes cibles (exposition unique)
EU hazard label	-
Specific concentration limits	STOT SE 3;H335: C ≥ 25 % Eye Irrit.2;H319: C ≥ 25 %
M factor	-
Acute toxicity estimate	-

ECHA sheet

Hazard statement - Code	H351
Hazard statement - Text	Susceptible de provoquer le cancer (indiquer la voie d'exposition s'il est formellement prouvé qu'aucune autre voie d'exposition ne conduit au même danger)
Hazard class(es)	Cancerogénicité
EU hazard label	-
Specific concentration limits	STOT SE 3;H335: C ≥ 25 % Eye Irrit.2;H319: C ≥ 25 %
M factor	-
Acute toxicity estimate	-

ECHA sheet

Regulations

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Règlement CLP - Annexe VI - Classification et étiquetage harmonisés pour certaines substances dangereuses

Physico Chemistry

Last verification the 26/11/2020

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Generalities

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Poids moléculaire

72.11 g/mol

Parameters table

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Parameters table
Value name	Value	Commentary	Source
Densité	0.887 -		UNEP
Pression de vapeur	21332 Pa	à 25°C	UNEP
Point de fusion	-108.5 °C		UNEP
Coefficient de partage octanol/eau (Log Kow)	0.46 -		UNEP

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Behavior

Last verification the 26/11/2020

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Matrixes

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Fresh water environment

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Parameters table
Value name	Value	Temperature	Pressure	Granulometry	Humidity	Guideline	ineris method	Commentary	Source
Coefficient de partage eau matière en suspension	0.5 L.kg^-1							calculé à partir du Koc (TGD)	UNEP

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Sediment fresh water environment

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Parameters table
Value name	Value	Temperature	Pressure	Granulometry	Humidity	Guideline	ineris method	Commentary	Source
Coefficient de partage eau sédiment	0.25 L.kg^-1							calculé à partir du Koc (TGD)	UNEP

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Terrestrial environment

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Parameters table
Value name	Value	Temperature	Pressure	Granulometry	Humidity	Guideline	ineris method	Commentary	Source
Coefficient de partage carbone organique/Eau (Koc)	5 L.kg^-1							estimé	UNEP
Coefficient de partage eau/sol	0.1 L.kg^-1							calculé à partir du Koc (TGD)	UNEP

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Persistence

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Biodegradability

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Parameters table
Value name	Value	Temperature	Pressure	Granulometry	Humidity	Guideline	ineris method	Commentary	Source
Biodégradabilité	facilement biodégradable -

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Abiotic degradability

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Parameters table
Value name	Value	Temperature	Pressure	Granulometry	Humidity	Guideline	ineris method	Commentary	Source
Photolyse	0.8 jour								UNEP

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Toxicology

Last verification the 26/11/2020

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Accidental values

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Other accidental thresholds

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Other accidental thresholds
ineris name	Duration	Value	Source	Status state	Commentary
ERPG-1	60 min	100 ppm	AIHA (2022)	Final
ERPG-2	60 min	500 ppm	AIHA (2022)	Final
ERPG-3	60 min	5000 ppm	AIHA (2022)	Final
IDLH	30 min	2000 ppm	NIOSH (1994)	Final
PAC-1	60 min	100 ppm	EHSS (2018)	Final	ERPG-1, ERPG-2, ERPG-3
PAC-2	60 min	500 ppm	EHSS (2018)	Final	ERPG-1, ERPG-2, ERPG-3
PAC-3	60 min	5000 ppm	EHSS (2018)	Final	ERPG-1, ERPG-2, ERPG-3

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Regulatory values

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Valeurs réglementaires
ineris name	Value	Source	Commentary	Critical effect retained	Status state	Duration of exposure	Environment	Exposure source	Factor	Management context	Age-Dependent Adjustments Factors	ADAF - Age range	ADAF - Value	ADAF - URL
VLEP CT	100 ppm	INRS (2024)	Valeur limite réglementaire contraignante		Final		Air	Lieux de travail
VLEP CT	300 mg.m^-3	INRS (2024)	Valeur limite réglementaire contraignante		Final		Air	Lieux de travail

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Reference values

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Other values of recognized organizations

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Autres valeurs des organismes reconnus
ineris name	Value	Source	Commentary	Critical effect retained	Status state	Duration of exposure	Environment	Exposure source	Factor	Management context	Age-Dependent Adjustments Factors	ADAF - Age range	ADAF - Value	ADAF - URL
RfC	2 mg.m^-3	US EPA (2012)		Increased liver weight and centrilobular cytomegaly, CNS effects (narcosis)	Final		Air ambiant
TCA	35 µg.m^-3	RIVM (2001)			Final		Air ambiant

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Ecotoxicology

Last verification the 26/11/2020

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Hazards

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Hazard values

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Environment

Valeurs de danger
ineris name	Specie	Value	Trofic level	Taxon	Matrix	Life stage	Effect	Detailed effect	Duration of exposure	ineris method	Guideline	Commentary	Source
CL/CE50		5930 mg.L^-1		Invertebré									UNEP
CL/CE50		2160 mg.L^-1		Poisson									UNEP

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Ecotoxicological values

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Guide values

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Environment

Valeurs guides
ineris name	Value	Matrix	Target	Critical effect retained	Duration of exposure	Factor	Commentary	Status state	Value retained by INERIS	Year	Source
PNEC chronique / AA-QSwater_eco	4.32 mg.L^-1	Eau douce				50	PNEC proposée par l'INERIS. - extrapolation		Yes		UNEP

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