Identification

Numero CAS

7803-51-2

Nom scientifique (FR)

Phosphine

Nom scientifique (EN)

Phosphane

Autres dénominations scientifiques (FR)

Hydrogène phosphoré; Trihydrure de phosphore; Phosphure d'hydrogène

Autres dénominations scientifiques (Autre langues)

phosphine ; phosphorus trihydride ; hydrogen phosphide ; fosforowodor ; phosphorated hydrogen ; phosphorous hydride ; phosphorwasserstoff

Code EC

232-260-8

Code SANDRE

-

Number CIPAC

-

Formule chimique brute

\(\ce{ PH3 }\)

Code InChlKey

XYFCBTPGUUZFHI-UHFFFAOYSA-N

Code SMILES

P

CLP classification

Type de classification

Harmonisée

ATP insertion

CLP00/ATP15

Description de la classification

Classification harmonisée selon réglement 1272/2008 ou CLP

Hazard statements
Hazard statement - Code H220
Hazard statement - Text Gaz extrêmement inflammable
Hazard class(es) Gaz inflammables
EU hazard label -
Specific concentration limits -
M factor -
Acute toxicity estimate Inhalation: ATE = 10 ppmV (Gases)
ECHA sheet
ECHA sheet

Regulations

Generalities

Poids moléculaire

34.04 g/mol

Parameters table

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Hydrosolubilité 0.4 g.L-1
20°C
INERIS (2008)
Densité 1.146 -
20°C
INERIS (2006)
Densité 1.17 -
Pression de vapeur 4100000 Pa
20°C
INERIS (2008)
Point d'ébullition -87.8 °C INERIS (2008)
Point de fusion -134 °C INERIS (2008)
Coefficient de partage octanol/eau (Log Kow) 0.9 - Expérimentation ESIS (2011)
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Explosiveness

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Limite inférieure d'explosivité (LIE) 2 % INERIS (2008)
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Flammability

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Point éclair 51.6 °C
Coupelle fermée
INERIS (2008)
Température d'auto inflammation 100 °C INERIS (2008)
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Matrixes

Terrestrial environment

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Coefficient de partage carbone organique/Eau (Koc) 13.22 L.kg-1 Calcul EPA
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Bioaccumulation

Aquatic organisms

Organismes aquatiques
ineris name Specie Value Trofic level Taxon Matrix Life stage Effect Detailed effect Duration of exposure ineris method Guideline Commentary Source
Bioaccumulation BCF 1.16 - Expérimentation ESIS (2011)
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Accidental values

French acute toxicity threshold values

Le rapport de valeurs seuils de toxicité aiguë françaises est accessible dans la rubrique « Archives ». L’intégralité des rapports de valeurs seuils de toxicité aiguë françaises actuellement en vigueur est consultable dans le tableau des VSTAF.

French acute toxicity threshold values
ineris name Unit 1 min 10 min 20 min 30 min 60 min 120 min 240 min 480 min Source Status state Commentary
SELS (SELS 5%) mg.m-3 ND 18612 4702 2103 531 135 33 8 Final
Non Significatif
SELS (SELS 5%) ppm ND 13390 3383 1513 382 97 24 6 Final
Non Significatif
SPEL (SEL 1%) mg.m-3 ND 17165 4337 1939 491 124 32 8 Final
Non Significatif
SPEL (SEL 1%) ppm ND 12349 3120 1395 353 89 23 6 Final
Non Significatif
SEI mg.m-3 ND 1907 482 215 54 14 4 1,5 Final
Non Significatif
SEI ppm ND 1372 347 155 39 10 3 1 Final
Non Significatif
SER mg.m-3 ND ND ND ND ND ND ND ND Final
Non Déterminé
SER ppm ND ND ND ND ND ND ND ND Final
Non Déterminé
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Other accidental thresholds

Other accidental thresholds
ineris name Duration Value Source Status state Commentary
AEGL-1 10 min NR ppm EPA Final
Not recommended due to insufficient data
AEGL-1 30 min NR ppm EPA Final
Not recommended due to insufficient data
AEGL-1 60 min NR ppm EPA Final
Not recommended due to insufficient data
AEGL-1 240 min NR ppm EPA Final
Not recommended due to insufficient data
AEGL-1 480 min NR ppm EPA Final
Not recommended due to insufficient data
AEGL-2 10 min 4 ppm EPA Final
AEGL-2 30 min 4 ppm EPA Final
AEGL-2 60 min 2 ppm EPA Final
AEGL-2 240 min 0,5 ppm EPA Final
AEGL-2 480 min 0,25 ppm EPA Final
AEGL-3 10 min 7,2 ppm EPA Final
AEGL-3 30 min 7,2 ppm EPA Final
AEGL-3 60 min 3,6 ppm EPA Final
AEGL-3 240 min 0,9 ppm EPA Final
AEGL-3 480 min 0,45 ppm EPA Final
ERPG-2 60 min 0,5 ppm AIHA (2022) Final
ERPG-3 60 min 5 ppm AIHA (2022) Final
IDLH 30 min 50 ppm NIOSH (1994) Final
PAC-1 60 min 1 ppm EHSS (2018) Final
TLV-STEL, AEGL-2, AEGL-3
PAC-2 60 min 2 ppm EHSS (2018) Final
TLV-STEL, AEGL-2, AEGL-3
PAC-3 60 min 3,6 ppm EHSS (2018) Final
TLV-STEL, AEGL-2, AEGL-3
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Regulatory values

Valeurs réglementaires
ineris name Value Source Commentary Critical effect retained Status state Duration of exposure Environment Exposure source Factor Management context Age-Dependent Adjustments Factors ADAF - Age range ADAF - Value ADAF - URL
VLEP CT 0,2 ppm INRS (2024)
Valeur limite réglementaire indicative
Final Air Lieux de travail
VLEP CT 0,28 mg.m-3 INRS (2024)
Valeur limite réglementaire indicative
Final Air Lieux de travail
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Reference values

Other values of recognized organizations

Autres valeurs des organismes reconnus
ineris name Value Source Commentary Critical effect retained Status state Duration of exposure Environment Exposure source Factor Management context Age-Dependent Adjustments Factors ADAF - Age range ADAF - Value ADAF - URL
RfC 0,0003 mg.m-3 US EPA (2025) Decreased body weight Final Air ambiant
REL 0,8 µg.m-3 OEHHA (2002) Decreased body weight gain in mice Final Air ambiant
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Bibliography

Documents

PDF
7803-51-2 -- Phosphine -- VSTAF
Published the 24/10/2008
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PDF
7803-51-2 -- Phosphine -- VSTAF-Rapp
Published the 13/03/2008
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