Identification

Numero CAS

75-44-5

Nom scientifique (FR)

Phosgène

Nom scientifique (EN)

carbonyl dichloride

Autres dénominations scientifiques (FR)

Chlorure de carbonyle; Dichlorure de carbonyle; Carbone (oxychlorure de)

Autres dénominations scientifiques (Autre langues)

phosgene ; carbonyl chloride ; chloroformyl chloride ; carbon dichloride oxide ; carbon oxychloride ; carbonic acid dichloride ; carbonic chloride ; carbonic dichloride ; carbonio (ossicloruro di) ; carbonyl dichloride ; carbonylchlorid ; fosgeen ; fosgen ; fosgene ; koolstofoxychloride

Code EC

200-870-3

Code SANDRE

-

Number CIPAC

-

Formule chimique brute

\(\ce{ COCl2 }\)

Code InChlKey

YGYAWVDWMABLBF-UHFFFAOYSA-N

Code SMILES

ClC(Cl)=O

CLP classification

Type de classification

Harmonisée

ATP insertion

CLP00

Description de la classification

Classification harmonisée selon réglement 1272/2008 ou CLP

Hazard statements
Hazard statement - Code H314
Hazard statement - Text Provoque de graves brûlures de la peau et de graves lésions des yeux.
Hazard class(es) Corrosion / Irritation cutanée
EU hazard label -
Specific concentration limits -
M factor -
Acute toxicity estimate -
ECHA sheet
ECHA sheet

Regulations

Generalities

Poids moléculaire

98.92 g/mol

Parameters table

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Hydrosolubilité 6.83 g.L-1
25°C
INERIS (2008)
Densité 3.41 - INERIS (2008)
Pression de vapeur 162000 Pa
20°C
INERIS (2008)
Concentration de vapeur saturante 1580290 ppm
20°C
INERIS (2008)
Concentration de vapeur saturante 6495 g.cm-3
20°C
INERIS (2008)
Point d'ébullition 8.2 °C INERIS (2008)
Point de fusion -118 °C INERIS (2008)
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Bibliography

Accidental values

French acute toxicity threshold values

Le rapport de valeurs seuils de toxicité aiguë françaises est accessible dans la rubrique « Archives ». L’intégralité des rapports de valeurs seuils de toxicité aiguë françaises actuellement en vigueur est consultable dans le tableau des VSTAF.

French acute toxicity threshold values
ineris name Unit 1 min 10 min 20 min 30 min 60 min 120 min 240 min 480 min Source Status state Commentary
SELS (SELS 5%) mg.m-3 770 61 25 12 4 ND ND ND Final
Non Déterminé
SELS (SELS 5%) ppm 190 15 6 3 1 ND ND ND Final
Non Déterminé
SPEL (SEL 1%) mg.m-3 607,5 40,5 16 8 4 ND ND ND Final
Non Déterminé
SPEL (SEL 1%) ppm 150 10 4 2 1 ND ND ND Final
Non Déterminé
SEI mg.m-3 121,5 12 6 4 2 ND ND ND Final
Non Déterminé
SEI ppm 30 3 1,5 1 0,5 ND ND ND Final
Non Déterminé
SER mg.m-3 ND ND ND ND ND ND ND ND Final
Non Déterminé
SER ppm ND ND ND ND ND ND ND ND Final
Non Déterminé
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Other accidental thresholds

Other accidental thresholds
ineris name Duration Value Source Status state Commentary
AEGL-1 10 min NR ppm EPA Final
Not recommended due to insufficient data
AEGL-1 30 min NR ppm EPA Final
Not recommended due to insufficient data
AEGL-1 60 min NR ppm EPA Final
Not recommended due to insufficient data
AEGL-1 240 min NR ppm EPA Final
Not recommended due to insufficient data
AEGL-1 480 min NR ppm EPA Final
Not recommended due to insufficient data
AEGL-2 10 min 0,6 ppm EPA Final
AEGL-2 30 min 0,6 ppm EPA Final
AEGL-2 60 min 0,3 ppm EPA Final
AEGL-2 240 min 0,08 ppm EPA Final
AEGL-2 480 min 0,04 ppm EPA Final
AEGL-3 10 min 3,6 ppm EPA Final
AEGL-3 30 min 1,5 ppm EPA Final
AEGL-3 60 min 0,75 ppm EPA Final
AEGL-3 240 min 0,2 ppm EPA Final
AEGL-3 480 min 0,09 ppm EPA Final
ERPG-1 60 min ND - AIHA (2022) Final
ERPG-2 60 min 1,5 ppm AIHA (2022) Final
ERPG-3 60 min 5 ppm AIHA (2022) Final
IDLH 30 min 2 ppm NIOSH (1994) Final
PAC-1 60 min 0,027 ppm EHSS (2018) Final
AEGL-2/11, AEGL-2, AEGL-3
PAC-2 60 min 0,3 ppm EHSS (2018) Final
AEGL-2/11, AEGL-2, AEGL-3
PAC-3 60 min 0,75 ppm EHSS (2018) Final
AEGL-2/11, AEGL-2, AEGL-3
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Regulatory values

Valeurs réglementaires
ineris name Value Source Commentary Critical effect retained Status state Duration of exposure Environment Exposure source Factor Management context Age-Dependent Adjustments Factors ADAF - Age range ADAF - Value ADAF - URL
VLEP CT 0,1 ppm INRS (2024)
Valeur limite réglementaire contraignante
Final Air Lieux de travail
VLEP CT 0,4 mg.m-3 INRS (2024)
Valeur limite réglementaire contraignante
Final Air Lieux de travail
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Reference values

Other values of recognized organizations

Autres valeurs des organismes reconnus
ineris name Value Source Commentary Critical effect retained Status state Duration of exposure Environment Exposure source Factor Management context Age-Dependent Adjustments Factors ADAF - Age range ADAF - Value ADAF - URL
REL 4 µg.m-3 OEHHA (2008) minor damage to the lower airways Final Air ambiant
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Bibliography

Documents

PDF
75-44-5 -- Phosgène -- VSTAF-Rapp
Published the 31/10/2023
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PDF
75-44-5 -- Phosgène -- VSTAF-Rapp-comp
Published the 31/10/2023
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PDF
75-44-5 -- Phosgène -- VSTAF
Published the 24/10/2008
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