Identification

Numero CAS

68-12-2

Nom scientifique (FR)

N,N-Diméthylformamide

Nom scientifique (EN)

N,N-dimethylformamide

Autres dénominations scientifiques (Autre langues)

n,n-dimethylformamide ; dmf ; n-formyldimethylamine ; dimethyl formamide ; dimethylamid kyseliny mravenci ; dimethylformamid ; dimetilformamide ; dimetylformamidu ; dwumetyloformamid ; formamide, n,n-dimethyl- ; formic acid, amide, n,n-dimethyl- ; n,n-dimethyl formamide ; n,n-dimethylmethanamide ; n,n-dimetilformamida

Code EC

200-679-5

Code SANDRE

5314

Number CIPAC

-

Formule chimique brute

\(\ce{ C3H7NO }\)

Code InChlKey

ZMXDDKWLCZADIW-UHFFFAOYSA-N

Code SMILES

C(=O)N(C)C

CLP classification

Type de classification

Harmonisée

ATP insertion

CLP00

Description de la classification

Classification harmonisée selon réglement 1272/2008 ou CLP

Hazard statements
Hazard statement - Code H312
Hazard statement - Text Nocif par contact cutané
Hazard class(es) Toxicité aiguë
EU hazard label -
Hazard statement - Code H319
Hazard statement - Text Provoque une sévère irritation des yeux
Hazard class(es) Lésions oculaires graves/irritation oculaire
EU hazard label -
Hazard statement - Code H332
Hazard statement - Text Nocif par inhalation
Hazard class(es) Toxicité aiguë
EU hazard label -
Specific concentration limits -
M factor -
Acute toxicity estimate -
ECHA sheet
ECHA sheet

Regulations

Generalities

Poids moléculaire

73.09 g/mol

Parameters table

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Densité 0.95 - UNEP (2004) p.27
Pression de vapeur 350 Pa
à 20°C
UNEP (2004) p.27
Point de fusion -61 °C UNEP (2004) p.27
Constante de Henry 0.00747 Pa.m3.mol-1
mesurée à 25°C
UNEP (2004) p.27
Coefficient de partage octanol/eau (Log Kow) -0.85 -
mesuré à 25°C
UNEP (2004) p.27
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Bibliography

Matrixes

Fresh water environment

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Coefficient de partage eau matière en suspension 0.378 L.kg-1
calculé à partir du Koc (TGD)
UNEP (2004) p.27
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Sediment fresh water environment

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Coefficient de partage eau sédiment 0.189 L.kg-1
calculé à partir du Koc (TGD)
UNEP (2004) p.27
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Terrestrial environment

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Coefficient de partage carbone organique/Eau (Koc) 3.78 L.kg-1
calculé à partir du Kow
UNEP (2004) p.27
Coefficient de partage eau/sol 0.076 L.kg-1
calculé à partir du Koc (TGD)
UNEP (2004) p.27
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Persistence

Biodegradability

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Biodégradabilité facilement biodégradable -
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Abiotic degradability

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Photolyse 0.083 jour UNEP (2004) p.27
Photolyse 50 jour UNEP (2004) p.27
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Bioaccumulation

Aquatic organisms

Organismes aquatiques
ineris name Specie Value Trofic level Taxon Matrix Life stage Effect Detailed effect Duration of exposure ineris method Guideline Commentary Source
Bioaccumulation BCF 0.3 -
Cyprinus carpio - poisson - valeur minimale mesurée - 56 jours à 25°C
UNEP (2004) p.27
Bioaccumulation BCF 0.800018445 - Expérimentation EPA
Bioaccumulation BCF 1.2 -
Cyprinus carpio - poisson - valeur maximale mesurée - 56 jours à 25°C
UNEP (2004) p.27
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Accidental values

French acute toxicity threshold values

Le rapport de valeurs seuils de toxicité aiguë françaises est accessible dans la rubrique « Archives ». L’intégralité des rapports de valeurs seuils de toxicité aiguë françaises actuellement en vigueur est consultable dans le tableau des VSTAF.

French acute toxicity threshold values
ineris name Unit 1 min 10 min 20 min 30 min 60 min 120 min 240 min 480 min Source Status state Commentary
SELS (SELS 5%) mg.m-3 ND ND ND ND ND ND ND ND Final
Les données disponibles ne permettent pas la détermination des SELS selon la méthodologie Française
SELS (SELS 5%) ppm ND ND ND ND ND ND ND ND Final
Les données disponibles ne permettent pas la détermination des SELS selon la méthodologie Française
SPEL (SEL 1%) mg.m-3 ND ND ND ND ND ND ND ND Final
Les données disponibles ne permettent pas la détermination des SPEL selon la méthodologie Française
SPEL (SEL 1%) ppm ND ND ND ND ND ND ND ND Final
Les données disponibles ne permettent pas la détermination des SPEL selon la méthodologie Française
SEI mg.m-3 ND ND ND ND ND ND ND ND Final
Les données disponibles ne permettent pas la détermination des SEI selon la méthodologie Française
SEI ppm ND ND ND ND ND ND ND ND Final
Les données disponibles ne permettent pas la détermination des SEI selon la méthodologie Française
SER mg.m-3 502 233 185 161 129 102 81 42 Final
SER ppm 168 78 62 54 43 34 27 14 Final
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Other accidental thresholds

Other accidental thresholds
ineris name Duration Value Source Status state Commentary
AEGL-1 10 min NR ppm EPA Final
Not recommended due to insufficient data
AEGL-1 30 min NR ppm EPA Final
Not recommended due to insufficient data
AEGL-1 60 min NR ppm EPA Final
Not recommended due to insufficient data
AEGL-1 240 min NR ppm EPA Final
Not recommended due to insufficient data
AEGL-1 480 min NR ppm EPA Final
Not recommended due to insufficient data
AEGL-2 10 min 110 ppm EPA Final
AEGL-2 30 min 110 ppm EPA Final
AEGL-2 60 min 91 ppm EPA Final
AEGL-2 240 min 57 ppm EPA Final
AEGL-2 480 min 38 ppm EPA Final
AEGL-3 10 min 970 ppm EPA Final
AEGL-3 30 min 670 ppm EPA Final
AEGL-3 60 min 530 ppm EPA Final
AEGL-3 240 min 280 ppm EPA Final
AEGL-3 480 min 140 ppm EPA Final
ERPG-1 60 min 2 ppm AIHA (2022) Final
ERPG-2 60 min 100 ppm AIHA (2022) Final
ERPG-3 60 min 500 ppm AIHA (2022) Final
IDLH 30 min 500 ppm NIOSH (1994) Final
PAC-1 60 min 2 ppm EHSS (2018) Final
ERPG-1, AEGL-2, AEGL-3
PAC-2 60 min 91 ppm EHSS (2018) Final
ERPG-1, AEGL-2, AEGL-3
PAC-3 60 min 530 ppm EHSS (2018) Final
ERPG-1, AEGL-2, AEGL-3
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Regulatory values

Valeurs réglementaires
ineris name Value Source Commentary Critical effect retained Status state Duration of exposure Environment Exposure source Factor Management context Age-Dependent Adjustments Factors ADAF - Age range ADAF - Value ADAF - URL
VLEP CT 30 mg.m-3 INRS (2024)
Valeur limite réglementaire contraignante
Final Air Lieux de travail
VLEP CT 10 ppm INRS (2024)
Valeur limite réglementaire contraignante
Final Air Lieux de travail
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Reference values

Other values of recognized organizations

Autres valeurs des organismes reconnus
ineris name Value Source Commentary Critical effect retained Status state Duration of exposure Environment Exposure source Factor Management context Age-Dependent Adjustments Factors ADAF - Age range ADAF - Value ADAF - URL
RfC 0,03 mg.m-3 US EPA (1987) Digestive disturbances and minimal hepatic changes suggestive of liver abnormalities Final Air ambiant
CT 0,1 mg.m-3 OMS CICAD (2001)
0,03 ppm
augmentation du taux sérique des enzymes hépatiques Final Air ambiant
REL 80 µg.m-3 OEHHA (2003) Liver dysfunction and respiratory irritation in humans Final Air ambiant
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Hazards

Hazard values

Valeurs de danger
ineris name Specie Value Trofic level Taxon Matrix Life stage Effect Detailed effect Duration of exposure ineris method Guideline Commentary Source
CL/CE50 >1000 mg.L-1 Algue UNEP (2004) p.27
CL/CE50 >100 mg.L-1 Invertebré UNEP (2004) p.27
CL/CE50 7100 mg.L-1 Poisson UNEP (2004) p.27
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Ecotoxicological values

Guide values

Valeurs guides
ineris name Value Matrix Target Critical effect retained Duration of exposure Factor Commentary Status state Value retained by INERIS Year Source
PNEC chronique / AA-QSwater_eco 22.8 mg.L-1 Eau douce 50
extrapolation
Yes UNEP (2004) p.27
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Documents

PDF
68-12-2--N,N-diméthylformamide--VSTAF-Rapp.pdf
Published the 21/06/2022
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