Peroxyde d'hydrogene (7722-84-1)

General informations

Last verification the 13/04/2018

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Identification

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Numero CAS

7722-84-1

Nom scientifique (FR)

Péroxyde d'hydrogène

Nom scientifique (EN)

NA

Autres dénominations scientifiques (Autre langues)

hydroperoxyde ; hydroperoxide ; hydrogen dioxide ; dihydrogen dioxide ; perossido di idrogeno ; wasserstoffperoxid ; waterstofperoxyde

Code EC

231-765-0

Code SANDRE

1849

Number CIPAC

-

Formule chimique brute

\(\ce{ H2O2 }\)

Code InChlKey

MHAJPDPJQMAIIY-UHFFFAOYSA-N

Code SMILES

OO

Families

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Usage families

Bactéricide

CLP classification

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Type de classification

Harmonisée

ATP insertion

CLP00

Description de la classification

Classification harmonisée selon réglement 1272/2008 ou CLP

Hazard statements

H271

H314

Toxique, irritant, sensibilisant, narcotique.

H302

H332

Sensibilisant, cancérogène, mutagène, reprotoxique

Hazard statement - Code	H271
Hazard statement - Text	Peut provoquer un incendie ou une explosion ; comburant puissant
Hazard class(es)	Matières solides et liquides comburants
EU hazard label	-
Specific concentration limits	Ox. Liq. 1;H271: C ≥ 70 %** Ox. Liq. 2;H272: 50 % ≤ C < 70 % ** Skin Corr. 1A;H314: C ≥ 70 % Skin Corr. 1B;H314: 50 % ≤ C < 70 % Skin Irrit. 2;H315: 35 % ≤ C < 50 % Eye Dam. 1;H318: 8 % ≤ C < 50 % Eye Irrit. 2;H319: 5 % ≤ C < 8 %
M factor	-
Acute toxicity estimate	-

ECHA sheet

Hazard statement - Code	H314
Hazard statement - Text	Provoque de graves brûlures de la peau et de graves lésions des yeux.
Hazard class(es)	Corrosion / Irritation cutanée
EU hazard label	-
Specific concentration limits	Ox. Liq. 1;H271: C ≥ 70 %** Ox. Liq. 2;H272: 50 % ≤ C < 70 % ** Skin Corr. 1A;H314: C ≥ 70 % Skin Corr. 1B;H314: 50 % ≤ C < 70 % Skin Irrit. 2;H315: 35 % ≤ C < 50 % Eye Dam. 1;H318: 8 % ≤ C < 50 % Eye Irrit. 2;H319: 5 % ≤ C < 8 %
M factor	-
Acute toxicity estimate	-

ECHA sheet

Hazard statement - Code	H302
Hazard statement - Text	Nocif en cas d'ingestion
Hazard class(es)	Toxicité aiguë
EU hazard label	-

Hazard statement - Code	H332
Hazard statement - Text	Nocif par inhalation
Hazard class(es)	Toxicité aiguë
EU hazard label	-
Specific concentration limits	Ox. Liq. 1;H271: C ≥ 70 %** Ox. Liq. 2;H272: 50 % ≤ C < 70 % ** Skin Corr. 1A;H314: C ≥ 70 % Skin Corr. 1B;H314: 50 % ≤ C < 70 % Skin Irrit. 2;H315: 35 % ≤ C < 50 % Eye Dam. 1;H318: 8 % ≤ C < 50 % Eye Irrit. 2;H319: 5 % ≤ C < 8 %
M factor	-
Acute toxicity estimate	-

ECHA sheet

Regulations

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Règlement CLP - Annexe VI - Classification et étiquetage harmonisés pour certaines substances dangereuses

Physico Chemistry

Last verification the 13/04/2018

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Generalities

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Poids moléculaire

34.02 g/mol

Parameters table

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Parameters table
Value name	Value	ineris method	Commentary	Source
Densité	1.4425 -			ECB (2003) Vol.38 p.246
Pression de vapeur	300 Pa		à 25°C	ECB (2003) Vol.38 p.246
Point de fusion	-0.415 °C			ECB (2003) Vol.38 p.246
Constante de Henry	0.00075 Pa.m³.mol^-1		mesurée, 20°C	ECB (2003) Vol.38 p.246
Coefficient de partage octanol/eau (Log Kow)	-1.57 -		calculée	ECB (2003) Vol.38 p.246
Coefficient de partage octanol/eau (Log Kow)	-1.57 -	Expérimentation		Opasnet contributors

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Behavior

Last verification the 13/04/2018

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Matrixes

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Fresh water environment

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Parameters table
Value name	Value	Temperature	Pressure	Granulometry	Humidity	Guideline	ineris method	Commentary	Source
Coefficient de partage eau matière en suspension	0.02 L.kg^-1							calculé à partir du Koc (TGD)	ECB (2003) Vol.38 p.246

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Sediment fresh water environment

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Parameters table
Value name	Value	Temperature	Pressure	Granulometry	Humidity	Guideline	ineris method	Commentary	Source
Coefficient de partage eau sédiment	0.01 L.kg^-1							calculé à partir du Koc (TGD)	ECB (2003) Vol.38 p.246

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Terrestrial environment

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Parameters table
Value name	Value	Temperature	Pressure	Granulometry	Humidity	Guideline	ineris method	Commentary	Source
Coefficient de partage carbone organique/Eau (Koc)	0.2 L.kg^-1							estimé avec QSAR	ECB (2003) Vol.38 p.246
Coefficient de partage eau/sol	0.004 L.kg^-1							calculé à partir du Koc (TGD)	ECB (2003) Vol.38 p.246

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Persistence

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Biodegradability

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Parameters table
Value name	Value	Temperature	Pressure	Granulometry	Humidity	Guideline	ineris method	Commentary	Source
Biodégradabilité	facilement biodégradable -

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Abiotic degradability

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Parameters table
Value name	Value	Temperature	Pressure	Granulometry	Humidity	Guideline	ineris method	Commentary	Source
Photolyse	1 jour								ECB (2003) Vol.38 p.246

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Fresh water environment

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Parameters table
Value name	Value	Temperature	Pressure	Granulometry	Humidity	Guideline	ineris method	Commentary	Source
Temps de demie vie eau douce	5 jour							pire cas, dans les eaux de surface	ECB (2003) Vol.38 p.246

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Sea water environment

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Parameters table
Value name	Value	Temperature	Pressure	Granulometry	Humidity	Guideline	ineris method	Commentary	Source
Temps de demie vie eau de mer	2.5 jour							mesurée	ECB (2003) Vol.38 p.246

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Terrestrial environment

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Parameters table
Value name	Value	Temperature	Pressure	Granulometry	Humidity	Guideline	ineris method	Commentary	Source
Temps de demie vie terrestre	0.5 jour								ECB (2003) Vol.38 p.246

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Bioaccumulation

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Aquatic organisms

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Organismes aquatiques
ineris name	Specie	Value	Trofic level	Taxon	Matrix	Life stage	Effect	Detailed effect	Duration of exposure	ineris method	Guideline	Commentary	Source
Bioaccumulation BCF		1.4 -										poisson - valeur calculée - TGD	ECB (2003) Vol.38 p.246

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Terrestrial organisms

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Organismes terrestres
ineris name	Specie	Value	Trofic level	Taxon	Matrix	Life stage	Effect	Detailed effect	Duration of exposure	ineris method	Guideline	Commentary	Source
Bioaccumulation BCF		3.3 -										ver de terre - valeur calculée - TGD	ECB (2003) Vol.38 p.246

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Toxicology

Last verification the 13/04/2018

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Accidental values

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Other accidental thresholds

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Other accidental thresholds
ineris name	Duration	Value	Source	Status state	Commentary
ERPG-1	60 min	10 ppm	AIHA (2022)	Final
ERPG-2	60 min	50 ppm	AIHA (2022)	Final
ERPG-3	60 min	100 ppm	AIHA (2022)	Final
IDLH	30 min	75 ppm	NIOSH (1994)	Final
PAC-1	60 min	10 ppm	EHSS (2018)	Final	ERPG-1, ERPG-2, ERPG-3
PAC-2	60 min	50 ppm	EHSS (2018)	Final	ERPG-1, ERPG-2, ERPG-3
PAC-3	60 min	100 ppm	EHSS (2018)	Final	ERPG-1, ERPG-2, ERPG-3

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Regulatory values

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Valeurs réglementaires
ineris name	Value	Source	Commentary	Critical effect retained	Status state	Duration of exposure	Environment	Exposure source	Factor	Management context	Age-Dependent Adjustments Factors	ADAF - Age range	ADAF - Value	ADAF - URL
VLEP 8h	1 ppm	INRS (2024)	Valeur limite admise (circulaire)		Final		Air	Lieux de travail
VLEP 8h	1,5 mg.m^-3	INRS (2024)	Valeur limite admise (circulaire)		Final		Air	Lieux de travail

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Ecotoxicology

Last verification the 13/04/2018

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Hazards

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Hazard values

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Environment

Valeurs de danger
ineris name	Value	Taxon	Source
CL/CE50	1.6 mg.L^-1	Algue	ECB (2003) Vol.38 p.246
CL/CE50	2 mg.L^-1	Invertebré	ECB (2003) Vol.38 p.246
CL/CE50	16.4 mg.L^-1	Poisson	ECB (2003) Vol.38 p.246
CL/CE50	1.38 mg.L^-1	Algue	ECB (2003) Vol.38 p.246

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Ecotoxicological values

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Guide values

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Environment

Valeurs guides
ineris name	Value	Matrix	Target	Critical effect retained	Duration of exposure	Factor	Commentary	Status state	Value retained by INERIS	Year	Source
PNEC	4.66 mg.L^-1	Station d'épuration				100	extrapolation		Yes		ECB (2003) Vol.38 p.246
PNEC chronique / AA-QSwater_eco	0.01 mg.L^-1	Eau douce				10	extrapolation		Yes		ECB (2003) Vol.38 p.246

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