Identification

Numero CAS

56-72-4

Nom scientifique (FR)

Coumaphos

Nom scientifique (EN)

3-chloro-7-diethoxyphosphinothioyloxy-4-methylchromen-2-one

Autres dénominations scientifiques (FR)

Thiophosphate de O,O-diéthyle et de O-3-chloro-4-méthyl-coumarine-7-yle

Autres dénominations scientifiques (Autre langues)

phosphorothioic acid o-(3-chloro-4-methyl-2-oxo-2h-1-benzopyran-7-yl) o,o-diethyl ester ; 3-chloro-4-methyl-7-coumarinyl diethyl phosphorothioate ; 3-chloro-4-methyl-7-hydroxycoumarin diethyl thiophosphoric acid ester ; 3-chloro-7-diethoxyphosphinothioyloxy-4-methylcoumarin ; 3-chloro-7-hydroxy-4-methyl-coumarin o,o-diethyl phosphorothioate ; coumarin, 3-chloro-7-hydroxy-4-methyl-, o-ester with o,o-diethyl phosphorothioate ; cumafos ; diethyl-o(3-chloro-4-methyl-7-coumarinyl) phosphorothioate ; o,o-diaethyl-o-(3-chlor-4-methyl-cumarin-7-yl)-monothiophosphat ; o,o-diethyl o-(3-chloro-4-methyl-2-oxo-2h-benzopyran-7-yl)phosphorothioate ; o,o-diethyl o-(3-chloro-4-methylcoumarinyl-7) thiophosphate ; o,o-diethyl o-(3-chloro-4-methylumbelliferyl)phosphorothioate ; o,o-diethyl-o-(3-chloor-4-methyl-cumarin-7-yl)monothiofosfaat ; o-3-chloro-4-methyl-2-oxo-2h-chromen-7-yl o,o-diethyl phosphorothioate ; o,o-dietil-o-(3-cloro-4-metil-cumarin-7-il-monotiofosfato) ; o-(3-chloro-4-methyl-2-oxo-2h-1-benzopyran-7-yl) o,o-diethyl phosphorothioate ; o-(3-chloro-4-methyl-7-coumarinyl) o,o-diethylphosphorothioate ; o,o-diethyl o-(3-chloro-4-methyl-7-coumarinyl)phosphorothioate ; o-3-chloro-4-methylcoumarin-7-yl o,o-diethyl phosphorothioate ; phosphorothioic acid, o,o-diethyl ester, o-ester with 3-chloro-7-hydroxy-4-methylcoumarin ; phosphorothioic acid, o-(3-chloro-4-methyl-2-oxo-2h-1-benzopyran-7-yl) o,o-diethyl ester

Code EC

200-285-3

Code SANDRE

1682

Number CIPAC

-

Formule chimique brute

\(\ce{ C14H16ClO5PS }\)

Code InChlKey

BXNANOICGRISHX-UHFFFAOYSA-N

Code SMILES

S=P(OCC)(OCC)Oc1ccc2C(C)=C(Cl)C(=O)Oc2c1

CLP classification

Type de classification

Harmonisée

ATP insertion

CLP00

Description de la classification

Classification harmonisée selon réglement 1272/2008 ou CLP

Hazard statements
Hazard statement - Code H300
Hazard statement - Text Mortel en cas d'ingestion
Hazard class(es) Toxicité aiguë
EU hazard label -
Specific concentration limits -
M factor -
Acute toxicity estimate -
ECHA sheet

Generalities

Poids moléculaire

362.77 g/mol

Parameters table

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Hydrosolubilité 1.5 mg.L-1
à 20°C
INERIS
Densité 1.47 - INERIS
Pression de vapeur 1.33e-05 Pa
à 20°C
INERIS
Point de fusion 91 °C INERIS
Constante de Henry 0.0032 Pa.m3.mol-1
calculée à 20°C
INERIS
Coefficient de partage octanol/eau (Log Kow) 3.86 - Expérimentation Opasnet contributors
Coefficient de partage octanol/eau (Log Kow) 4.13 - INERIS
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Bibliography

Matrixes

Fresh water environment

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Coefficient de partage eau matière en suspension 380 L.kg-1
calculé à partir du Koc (TGD)
INERIS
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Sediment fresh water environment

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Coefficient de partage eau sédiment 190 L.kg-1
calculé à partir du Koc (TGD)
INERIS
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Terrestrial environment

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Coefficient de partage carbone organique/Eau (Koc) 3800 L.kg-1 INERIS
Coefficient de partage eau/sol 76 L.kg-1
calculé à partir du Koc (TGD)
INERIS
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Persistence

Abiotic degradability

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Hydrolyse 30 jour
valeur maximale à pH alcalin
INERIS
Hydrolyse 5 jour
à pH 7,3 à 22°C et à la lumière naturel
INERIS
Hydrolyse 59 jour
à pH 7,3 à 22°C et à l'obscurité
INERIS
Photolyse 1.375 jour INERIS
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Bioaccumulation

Aquatic organisms

Organismes aquatiques
ineris name Specie Value Trofic level Taxon Matrix Life stage Effect Detailed effect Duration of exposure ineris method Guideline Commentary Source
Bioaccumulation BCF 110 -
Leucisdus idus melanotus - poisson - valeur mesurée - 3 jours
INERIS
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Bibliography

Accidental values

Other accidental thresholds

Other accidental thresholds
ineris name Duration Value Source Status state Commentary
PAC-1 60 min 0,27 mg.m-3 EHSS (2018) Final
TEEL-2/11, LOC, rat 240-min LC50
PAC-2 60 min 3 mg.m-3 EHSS (2018) Final
TEEL-2/11, LOC, rat 240-min LC50
PAC-3 60 min 13 mg.m-3 EHSS (2018) Final
TEEL-2/11, LOC, rat 240-min LC50
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Reference values

ANSES and/or INERIS values

Valeurs de l'ANSES et/ou de l'INERIS
ineris name Value Organization choice Year of choice URL choice Source Commentary Critical effect retained Status state Duration of exposure Environment Exposure source Factor Management context Age-Dependent Adjustments Factors ADAF - Age range ADAF - Value ADAF - URL
VTR 0,5 µg.kg-1.j-1 Anses 2016 AUS Final Eau
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Bibliography

Hazards

Hazard values

Valeurs de danger
ineris name Specie Value Trofic level Taxon Matrix Life stage Effect Detailed effect Duration of exposure ineris method Guideline Commentary Source
CL/CE50 7.4e-05 mg.L-1 Invertebré INERIS
CL/CE50 0.34 mg.L-1 Poisson INERIS
CL/CE50 0.002 mg.L-1 Invertebré INERIS
CL/CE50 0.28 mg.L-1 Poisson INERIS
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Ecotoxicological values

Guide values

Valeurs guides
ineris name Value Matrix Target Critical effect retained Duration of exposure Factor Commentary Status state Value retained by INERIS Year Source
PNEC chronique / AA-QSwater_eco 3.4e-06 mg.L-1 Eau douce 10
extrapolation
Yes INERIS
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Bibliography