Identification

Numero CAS

101-77-9

Nom scientifique (FR)

4,4'-Méthylène dianiline

Nom scientifique (EN)

4-[(4-aminophenyl)methyl]aniline

Autres dénominations scientifiques (FR)

Diamino-4,4' diphénylméthane; 4,4'-Diaminodiphénylméthane; p,p'-Diaminodiphénylméthane;

Autres dénominations scientifiques (Autre langues)

4,4'-methylenedianiline ; 4,4'-methylenebisbenzenamine ; 4,4'-diamino ditan ; 4,4'-diaminodiphenylmethan ; 4,4'-diphenylmethanediamine ; 4,4'-methylene dianiline ; 4,4'-methylenebis(benzeneamine) ; 4,4'-methylenebisaniline ; 4,4-methylenedianiline ; 4-(4-aminobenzyl)aniline ; aniline, 4,4'-methylenedi- ; benzenamine, 4,4'-methylenebis- ; bis(4-aminophenyl)methane ; bis(p-aminophenyl)methane ; bis-p-aminofenylmethan ; bis-p-aminofenylmethan (cz) ; curithane ; di-(4-aminophenyl)methane ; dianilinemethane ; dianilinomethane ; methylenebis(aniline) ; p,p'-diaminodifenylmethan ; p,p'-diaminodifenylmethan (cz) ; p,p'-methylenedianiline ; [4-(4-aminobenzyl)phenyl]amine ; 4-[(4-aminophenyl)methyl]aniline ; 4,4'-diaminodiphenylmethan [de] ; 4,4'-dimethylenediamine ; 4,4'-methylene(bisaniline) ; 4,4'-methylenebis(aniline) ; bis-p-aminofenylmethan [cz] ; di(4-aminophenyl)methane ; methylenedianiline (van) ; p,p'-diaminodifenylmethan [cz] ; p-toluidine, .alpha.-(p-aminophenyl)- ; p-toluidine, alpha-(p-aminophenyl)-

Code EC

202-974-4

Code SANDRE

6640

Number CIPAC

-

Formule chimique brute

\(\ce{ C13H14N2 }\)

Code InChlKey

YBRVSVVVWCFQMG-UHFFFAOYSA-N

Code SMILES

c1(N)ccc(Cc2ccc(N)cc2)cc1

CLP classification

Type de classification

Harmonisée

ATP insertion

CLP00

Description de la classification

Classification harmonisée selon réglement 1272/2008 ou CLP

Hazard statements
Hazard statement - Code H317
Hazard statement - Text Peut provoquer une allergie cutanée
Hazard class(es) Sensibilisation respiratoire/cutanée
EU hazard label -
Specific concentration limits -
M factor -
Acute toxicity estimate -
ECHA sheet
ECHA sheet

Regulations

Generalities

Poids moléculaire

198.30 g/mol

Parameters table

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Hydrosolubilité 1250 mg.L-1
à 20°C
Densité 1.056 -
Pression de vapeur 2.87e-06 Pa
à 20°C
Point de fusion 89 °C
Constante de Henry 4.4e-07 Pa.m3.mol-1
Coefficient de partage octanol/eau (Log Kow) 1.59 -
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Matrixes

Fresh water environment

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Coefficient de partage eau matière en suspension 0.704 L.kg-1
calculé à partir du Koc (TGD)
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Sediment fresh water environment

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Coefficient de partage eau sédiment 0.352 L.kg-1
calculé à partir du Koc (TGD)
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Terrestrial environment

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Coefficient de partage carbone organique/Eau (Koc) 7.041 L.kg-1
Coefficient de partage eau/sol 0.141 L.kg-1
calculé à partir du Koc (TGD)
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Persistence

Biodegradability

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Biodégradabilité intrinsèquement biodégradable -
Avec un inoculum industriel adapté.
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Abiotic degradability

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Photolyse 0.53 jour
calculée
Photolyse 1900 jour
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Terrestrial environment

Parameters table
Value name Value Temperature Pressure Granulometry Humidity Guideline ineris method Commentary Source
Temps de demie vie terrestre 1000 jour
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Bioaccumulation

Aquatic organisms

Organismes aquatiques
ineris name Specie Value Trofic level Taxon Matrix Life stage Effect Detailed effect Duration of exposure ineris method Guideline Commentary Source
Bioaccumulation BCF 15.0003019 - Expérimentation EPA
Bioaccumulation BCF 45 -
poisson - valeur mesurée
Bioaccumulation BCF 800 -
organismes benthiques - valeur mesurée
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Bibliography

Accidental values

Other accidental thresholds

Other accidental thresholds
ineris name Duration Value Source Status state Commentary
PAC-1 60 min 0,1 ppm EHSS (2018) Final
PEL-STEL, TEEL-3/6, dog oral LDLo
PAC-2 60 min 3,4 ppm EHSS (2018) Final
PEL-STEL, TEEL-3/6, dog oral LDLo
PAC-3 60 min 20 ppm EHSS (2018) Final
PEL-STEL, TEEL-3/6, dog oral LDLo
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Regulatory values

Valeurs réglementaires
ineris name Value Source Commentary Critical effect retained Status state Duration of exposure Environment Exposure source Factor Management context Age-Dependent Adjustments Factors ADAF - Age range ADAF - Value ADAF - URL
VLEP 8h 0,08 mg.m-3 INRS (2024)
Valeur limite réglementaire indicative
Final Air Lieux de travail
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Reference values

Other values of recognized organizations

Autres valeurs des organismes reconnus
ineris name Value Source Commentary Critical effect retained Status state Duration of exposure Environment Exposure source Factor Management context Age-Dependent Adjustments Factors ADAF - Age range ADAF - Value ADAF - URL
REL 20 µg.m-3 OEHHA (2003) Ocular toxicity to the retinas of guinea pigs Final Air ambiant
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Hazards

Hazard values

Valeurs de danger
ineris name Specie Value Trofic level Taxon Matrix Life stage Effect Detailed effect Duration of exposure ineris method Guideline Commentary Source
CL/CE50 21 mg.L-1 Algue
CL/CE50 2.3 mg.L-1 Invertebré
CL/CE50 32 mg.L-1 Poisson
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Ecotoxicological values

Guide values

Valeurs guides
ineris name Value Matrix Target Critical effect retained Duration of exposure Factor Commentary Status state Value retained by INERIS Year Source
PNEC 1 mg.L-1 Station d'épuration 100
Supérieur à 1. - extrapolation
Yes ECB (2001) Vol.9 p.115
PNEC chronique / AA-QSwater_eco 0.003 mg.L-1 Eau douce 50
extrapolation
Yes ECB (2001) Vol.9 p.115
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